Gas Separations Perspectives

Compatibilized Immiscible Polymer Blends for Gas Separations

Membrane-based gas separation has attracted a great deal of attention recently due to the requirement for high purity gasses in industrial applications like fuel cells, and because of environment concerns, such as global warming. The current methods of cryogenic distillation and pressure swing adsorption are energy intensive and costly. Therefore, polymer membranes have emerged as a less energy...

Gas-phase separations of electrosprayed peptide libraries.

High-resolution ion mobility spectrometry has been combined with time-of-flight mass spectrometry for analysis of a combinatorial peptide library that is expected to contain 676 components. In this approach, the components of a mixture of three residue peptides, having the general form (D)Phe-Xxx-Xxx-CONH2 (where Xxx is randomized over 26 residues including 10 naturally occurring amino acids an...

Tunable Composite Membranes for Gas Separations

SHORT COMMUNICATION Gas-Phase Separations of Protease Digests

A mixture of peptides from a complete tryptic digest of ubiquitin has been analyzed by ion mobility/time-of-flight mass spectrometry techniques. All components of the mixture were electrosprayed and ions were separated in the gas phase based on differences in their mobilities through helium before being dispersed into a time-of-flight mass spectrometer for mass-to-charge analysis. The data show...

Optimal design of spiral-wound membrane networks for gas separations

An optimal design strategy for spiral-wound membrane networks based on an approximate permeator model and a mixedinteger nonlinear programming (MINLP) solution strategy is proposed. A general permeator system superstructure is used to embed a very large number of possible network con®gurations. The superstructure allows the development of a MINLP design strategy which simultaneously optimizes t...